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BL24 - CIRCE
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Endstations
NAPP

The Near-Ambient Pressure Photoemission (NAPP) endstation is an Ultra High Vacuum (UHV) setup equipped with a hemispherical electron energy analyzer for X-ray Photoelectron Spectroscopy (Phoibos NAP150 from SPECS) that can operate at a sample pressure range from UHV up to 25 mbar thanks to a differential pumping system which ensures a pressure difference of 109 between detector and sample (A differentially pumped electrostatic lens system for photoemission studies in the millibar range). Therefore the usual characterization capabilities of XPS are extended to the study of gas-solid and gas-liquid interphases, with applications for "in-situ" characterization of heterogeneous catalysts, corrosion processes, wetting, fuel cells, photovoltaics, etc.

Near Edge X-ray absorption (NEXAFS or XAS) is also possible either in Total Electron Yield mode (measuring sample current) or in Auger mode using the electron energy analyzer. A UHV gas inlet system (Puregas from SPECS) for dosing pure gases or gas mixtures in the analysis chamber, with purity level better than ppb, will be operative in the second half of 2017. This system will allow dosing up to three different gases simultaneously with automatic flow and pressure control. Additionally, for finer dosing, three leak valve lines are also available in the analysis chamber.

A mass spectrometer is installed in the second stage of the differential pumping system of the analyzer, making it possible to simultaneously analyze the reaction gases during the experiments in order to confirm gas composition and investigate reaction products.

A motorized 5-axes manipulator allows the variation of sample polar and azimuth angles in the analysis chamber. The incident photon beam is deflected 3o downwards, making possible to measure with the sample in horizontal position; this is of interest in the case of powder samples. It is also possible to transfer samples in horizontal position all the way to the measuring position.

Regarding electron emission geometry, the analyzer axis is at 54.7o with respect to the incident beam (Magic Angle for both linear vertical and horizontal light polarizations). During data acquisition, the samples can be heated up to approx. 1000 K either by means of an infrared laser or by using a sample holder with an encapsulated filament. For experiments requiring cooling, there is an alternative manipulator that allows cooling the sample down to -23 ˚C by using a Peltier element.

The NAPP setup also includes a surface science preparation chamber currently equipped with ion sputtering gun, LEED and a flange for the installation of evaporators. A quartz balance will be available in 2017. Other ports are available for installing additional equipment brought by the users (sample cleaver, etc).

PEEM

The PEEM endstation consists of an Elmitec LEEM/PEEM III with a Kirkpatrick-Baez refocusing mirror pair focusing the beam down to 12 x 36 µm2 (footprint on the sample). The microscope can be operated as LEEM, LEED, PEEM (X or UV) with a spatial resolution of 10 nm in LEEM and UV-PEEM modes and down to 20 nm in XPEEM. In X-PEEM mode, XMCD and XMLD effects can be used as mechanisms to reveal a ferromagnetic or anti-ferromagnetic contrast, while scanning the incoming photon energy or the electron analyzer energy, local XAS and XPS spectra with submicron spatial resolution and electron energy resolution ~ 0.2 eV can be obtained. Rotation of the manipulator around the surface normal permits any relative orientation of the polarization and the sample.

The measurement of temperature ranges from 100 K up to about 1500 K, while for preparation of short-time flashes of substrates it is possible for this range to go up to 2000 K. The sample holders are equipped with a filament for electron bombardment, a W:Re thermocouple, and two extra contacts. Special sample holders and HV rack inserts for in-situ application of small (bipolar) magnetic fields and voltages up to 220 V are now available.

Two ports in the PEEM chamber allow installation of custom equipment, e.g. e-beam evaporators for "in situ" layer growth with real time imaging or gas crackers for reactivity studies. Additional preparation options exist in the preparation chamber (ion sputtering gun, another port, for organic materials for example). Precision leak valves for gas dosing and residual gas analyzers are available on both chambers.

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Alba Synchrotron
Consortium for the Construction, Equipping and Exploitation of the Synchrotron Light Source (CELLS)

Synchrotron light source in Spain for discovering the secrets of life sciences, materials for energy, environment, nanomaterials, cultural heritage and many more.

Carrer de la Llum 2-26 08290 Cerdanyola del Vallès, Barcelona, Spain

How to arrive+34 93 592 43 00

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