An in depth understanding of the atomistic mechanism underlying different chemical processes
requires recording large sets of data under operando conditions yielding key information of the interface.
Thus, the desired parameters to be known include the chemical composition at the interface, chemical
states of the atoms and their variation as a result of the chemical or electrochemical reactions as well as
the structural evolution. Unfortunately the analytical techniques able to provide interface information are
very limited and hardly compatible with gases and liquids at high pressure [1,2] allowing usually only ex
situ characterizations leading to a loss of important information as in many cases the intermediates and
actives species cannot be “quenched” in post process analysis. X-ray spectroscopy techniques are able
to provide relevant information of the electronic structure in an element specific manner but real
interfaces are buried and most of the time in presence of gases and liquids electrolytes being
inaccessible directly to the common surface sensitive techniques like photoelectron spectroscopy
requiring new experimental strategies for their investigation under these conditions. In this talk I will
present some of the new approaches that I developed during the lasts years which allow the investigation
of the electronic structure variation of the catalysts and electrocatalysts under reaction conditions using
photoelectron spectroscopy, from gas phase up to bulk aqueous electrolyte. During these talk I will
illustrate quickly the capabilities of these setups using two examples, the selective hydrogenation of
alkynes on Pd catalyst (gas phase reactions) [3] and the electrocatalytic oxygen evolution on iridium
oxide electrocatalysts (liquid phase reactions) [4]. These results will be put in perspective with the future
3Sbar beamline highlighting the importance of a setup with its capabilities.